Re:
Well you live and learn. Didn't realise xo required narrower cables. I'm not 100% convinced this is the issue, as whilst I was cleaning and fettling, I moved the shifters further inwards and noticed after doing this, the paddle would occasionally catch the brake mount. I've adjusted accordingly and also flushed a bit so I'll see how it goes on the next ride. Still couldn't replicate the issue on the bike stand though.