PB Blaster
If the post is solid at the clamp, drill a small hole in the post and spray this stuff in the seat tube/post and then let her sit for a bit. Few Days maybe, reapply, and repeat.
http://blasterchemical.com/display.cfm?p=50003&pid=4
Then, mount the frame in a repair stand, such that the post is holding the bike to the stand, and orient the bike so that the frame is on it's side and pushing down on the headtube will apply a torsional force to the post. Finally, making sure that the stand is sturdy (you may need to weight it down to keep it from toppling, especially a folding type race stand), hang a heavy object from the headtube so that constant force is applied to twist the post out gradually, I like to use a concrete cinder block for the job, hanging from a padded bike security chain...protects the paint well.
Make sure the weight isn't far from the ground, because when the post breaks loose, you don't want to have the frame swing around in the stand so far that you prang it on something.
Sit back, wait about 3 days to a week, and BOING!...the post will pop loose. No need to pop a blood vessel in your skull twisting on the thing like a crazy man. Steel frames rust fast in Florida, and I've used this method on stuck posts many times and it almost always seems to work. Cutting out the post or resolving the matter to the vise always works too, but takes a hell of alot of work, and if you don't need the frame for a build right away, then let PB Blaster and gravity do the trick for you.
This method works for stuck bottom brackets too...just with some obvious variation in frame and weight placement, and tools.
PB Blaster is magical stuff.