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Introduced in 1935 and for many years at the forefront of alloy steel tubing technology, 531 cycle tubing has been superseded by more complex alloys and heat-treatment/cold-forming cycles as Reynolds continues to compete with other manufacturers of steel for the bicycle industry.[3]
531 tubing became the tubing-of-choice for most framebuilders at least partly because of the huge range of butting, diameters and thicknesses of tubes along with different stays and fork blades available - helped by the willingness of Reynolds to make special tubes for certain manufacturers. Reynolds also made up complete 'sets' of tubing for different cycling applications - for example 531c (Competition), 531st (Special Tourist), 531ATB (All Terrain Bike) and so-on. This flexibility made 531 still competitive even after the introduction of more advanced alloys. The widespread use of TIG and MIG welding in cycle manufacture became a problem as 531 reacted poorly to the higher temperatures produced and 531 has been gradually phased out as a result.[2]
The most common like-for-like replacements for 531 are Reynolds 520 and 525 - a Chrome-Molybdenum tubing with very similar characteristics, but in addition to brazing, can also be welded. The 520 tubing can often be seen on modern "fixie" bikes (urban "track" type bike frames), while the 525 with its thicker-walled seat stays is more for cyclo-cross and touring framesets.
The approximate alloying composition of 531 tubing is 1.5% Mn, 0.25% Mo, 0.35% C, and is similar to the old British BS970 En 16/18 steel (EN 16 is similar to grade BS970 605M36). Its mechanical properties and response to heat treatment are broadly similar to the AISI 4130 standard alloy steel, also used for bicycle frames, motorcycles, as well as aviation and motor-sport.[3] This material was used to form the front subframes on the Jaguar E-Type of the 1960s.[4]
Reynolds 531 is now only available by special order.[3] The nearest available stock material is BS4t45 to Bs5T100 in accordance with BS6S100 conditions.[5] (T45) Reynolds has superseded this tube set with a number of innovations such as Reynolds 753 and the more current 853. Reynolds also produces stainless steel tube sets for bicycle frame building - these are 925 and 953.