Well,
I ended up removing it. Sacrificial or not, this sucker was tricky. Obviously used the 'softly softly catchy monkey' approach so as not to terminally stuff the frame. Used a small one-ended hacksaw and carefully cut a lot of vertical cuts, then peeled back with a soft edged 'blade'. Patience was the key - and coffee! The shim itself had a machined surface to enable grip to the ti tube, not unlike the surface of a Thomson post, and was also affixed with I guess some type of Loctite. Will replace with alu shim then fit a USE post, I think. Thanks for all the tips and advice.