Ok - so I've had a long chat with John (the seatpostman) on Sunday. He'd already looked at my pics. He's a very decent chap, and was very helpful, but, the long and short of it, was that he has gone straight to caustic as the solution to remove the seatpost remnant! However, this is with a couple of proviso's that we're still looking at:
1 - His method of removal is purely tooling, and he agreed with me that the massive butt that's about 60mm into the top of my seat-tube, will make using his method extremely difficult and extremely expensive. He sort of implied that it just wouldn't work to be honest with you.
2 - It now makes sense why the expanding foam was squirted in. The utter tool that pushed the remnant of the post into the tube in the first place, had clearly had it stuck in the 60mm of "butted" 27.2mm section of the tube. Once the seatpin had been cut and knocked in, the main part of the seat-tube is way bigger (thinner) than the butted section, and it would have rattled around loose like a bitch - clearly this was simply to stop it rattling around. In itself, this is fairly useful, as once the foam has been dissolved (he thought I might be able to use ammonia to do this?), the remnant should likely be very loose in the tube, and should move around like a small tube, within a tube.
3 - He agreed with me that the bottom bracket shell probably does have a piece of pressed-in collar, which could well be an alloy that won't take kindly to the caustic. He recommended trying to get this pressed out, to make it nicer to get the caustic into the seat-tube in any case.
4 - It's looking more likely that the bottle bosses are ally. If I can get the bottom bracket collar pressed out, and feed a pipe into the seat-tube (with the frame inverted) and the seat-tube opening plugged and covered, and don't take the level of the tube above that, or particularly close to the upper bottle boss, they might live through it without too much damage! He did comment that these could be replaced if need be, but I'd still like to avoid that if I can!
5 - He was very confident that the 60mm seat-tube butted section was just pure Ti. He thought that the three holes that feed into two stays and the top tube, were a giveaway that there wasn't any sort of pressed in ally collar, as if there had been, you'd see a the "top hat" lip of the collar, sitting on the top of the seat-tube, and there is none on this frame.
Therefore, the best solution I've got at the moment, is to:
1 - Dissolve the remnants of the expanding foam with ammonia
2 - Eat that sucker out with a caustic concoction in an inverted frame, with the bottom bracket collar pressed out for access into the tube through the bottom bracket (and to stop the collar itself from being damaged by this process).
Any thoughts as I continue to mull this over?