SOLVED: How do I get this Syncros Cattlehead off my head tube/steerer tube?

Mallet sounds promising.😃

Also Aluminium expands much faster than steel, so some gentle heat will help, even boiling water.
Lacquer and paint are usually ok to 200⁰ if you want to get a blowtorch on it...
Oh, and the mallet!
I drop the forks into the bench vice with scrap cardboard to protect them, a wooden broomhandle is ok to a point - you need to bear in mind the equal and opposite reaction to any force, and what that might do to the paint!😬
 
Its the wrong way round for freezing spray (unlike a seatpost trapped in a steel seat tube)....although it may still crack the bond a bit.

The idea is freezing spray into the tube to shrink the steel.
But...
the steel shrinks much more slowly than the aluminium expands
Freezing spray changes the temperature by maybe 40⁰, whereas a blowtorch or even heat gun will take it up 160⁰+++

I've got freezing spray in the workshop. It's safer in many ways than flame, but it's comparatively disappointing in its effects.
 
SUCCESS!!

I removed the handlebar and cables, and used a large spanner wrapped in leftover leather scraps and a towel (for lack of a Mallet) and gave it a reasonably forgivable smack at a point where a sudden shock might evenly distribute that load and not do any damage to the stem itself.

It rotated upon the steerer tube by around 10 degrees. I tried using my hands to rotate it back to its original position, and before long, it slid off the steerer tube.

Thank you everyone for sharing your experience and wisdom. I’ll leave this post open for future readers to find.
 
SUCCESS!!

I removed the handlebar and cables, and used a large spanner wrapped in leftover leather scraps and a towel (for lack of a Mallet) and gave it a reasonably forgivable smack at a point where a sudden shock might evenly distribute that load and not do any damage to the stem itself.

It rotated upon the steerer tube by around 10 degrees. I tried using my hands to rotate it back to its original position, and before long, it slid off the steerer tube.

Thank you everyone for sharing your experience and wisdom. I’ll leave this post open for future readers to find.
The first rule of retro bike fettling is that you must get yourself a large mallet! 😂
 
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